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JEE Main PAPER - 1

JEE Main · 2018

180 questions · No login required

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  1. 1
    MCQ4 marks

    It is found that if a neutron suffers an elastic collinear collision with deuterium at rest, fractional loss of its energy is pdp_d  ; while for its similar collision with carbon nucleus at rest, fractional loss of energy is pcp_c  . The values of pdp_d   and pcp_c   are respectively:

    • A.(0, 0)
    • B.(0, 1)
    • C.(.89, .28)Correct
    • D.(.28, .89)
  2. 2
    MCQ4 marks

    The mass of a hydrogen molecule is 3.32×1027 kg3.32 \times 10^{-27} \text{ kg}  . If 102310^{23}   hydrogen molecules strike, per second, a fixed wall of area 2 cm22 \text{ cm}^2   at an angle of 4545^\circ   to the normal, and rebound elastically with a speed of 103 m/s10^3 \text{ m/s}  , then the pressure on the wall is nearly:

    • A.2.35×102 N/m22.35 \times 10^2 \text{ N/m}^2
    • B.4.70×102 N/m24.70 \times 10^2 \text{ N/m}^2
    • C.2.35×103 N/m22.35 \times 10^3 \text{ N/m}^2Correct
    • D.4.70×103 N/m24.70 \times 10^3 \text{ N/m}^2
  3. 3
    MCQ4 marks

    A solid sphere of radius rr   made of a soft material of bulk modulus KK   is surrounded by a liquid in a cylindrical container. A massless piston of area aa   floats on the surface of the liquid, covering entire cross section of cylindrical container. When a mass mm   is placed on the surface of the piston to compress the liquid, the fractional decrement in the radius of the sphere, (drr)\left(\frac{dr}{r}\right)  , is:

    • A.mg3Ka\frac{mg}{3Ka}Correct
    • B.mgKa\frac{mg}{Ka}
    • C.Kamg\frac{Ka}{mg}
    • D.Ka3mg\frac{Ka}{3mg}
  4. 4
    MCQ4 marks

    Two batteries with e.m.f. 12 V12 \text{ V}   and 13 V13 \text{ V}   are connected in parallel across a load resistor of 10Ω10 \, \Omega  . The internal resistances of the two batteries are 1Ω1 \, \Omega   and 2Ω2 \, \Omega   respectively. The voltage across the load lies between:

    • A.11.4 V11.4 \text{ V}   and 11.5 V11.5 \text{ V}
    • B.11.7 V11.7 \text{ V}   and 11.8 V11.8 \text{ V}
    • C.11.6 V11.6 \text{ V}   and 11.7 V11.7 \text{ V}
    • D.11.5 V11.5 \text{ V}   and 11.6 V11.6 \text{ V}Correct
  5. 5
    MCQ4 marks

    A particle is moving in a circular path of radius aa   under the action of an attractive potential U=k2r2U = -\frac{k}{2r^2}  . Its total energy is:

    • A.ZeroCorrect
    • B.32ka2-\frac{3}{2}\frac{k}{a^2}
    • C.k4a2-\frac{k}{4a^2}
    • D.k2a2\frac{k}{2a^2}
  6. 6
    MCQ4 marks

    Two masses m1=5 kgm_1 = 5 \text{ kg}   and m2=10 kgm_2 = 10 \text{ kg}  , connected by an inextensible string over a frictionless pulley, are moving as shown in the figure. The coefficient of friction of horizontal surface is 0.15. The minimum weight mm   that should be put on top of m2m_2   to stop the motion is:

    • A.43.3 kg43.3 \text{ kg}
    • B.10.3 kg10.3 \text{ kg}
    • C.18.3 kg18.3 \text{ kg}
    • D.27.3 kg27.3 \text{ kg}Correct
  7. 7
    MCQ4 marks

    If the series limit frequency of the Lyman series is νL\nu_L   then the series limit frequency of the Pfund series is:

    • A.νL/16\nu_L / 16
    • B.νL/25\nu_L / 25Correct
    • C.25νL25 \nu_L
    • D.16νL16 \nu_L
  8. 8
    MCQ4 marks

    Unpolarized light of intensity II   passes through an ideal polarizer A. Another identical polarizer B is placed behind A. The intensity of light beyond B is found to be I/2I/2  . Now another identical polarizer C is placed between A and B. The intensity beyond B is now found to be I/8I/8  . The angle between polarizer A and C is:

    • A.4545^\circCorrect
    • B.6060^\circ
    • C.00^\circ
    • D.3030^\circ
  9. 9
    MCQ4 marks

    An electron from various excited states of hydrogen atom emit radiation to come to the ground state. Let λn,λg\lambda_n, \lambda_g   be the de Broglie wavelength of the electron in the nthn^{th}   state and the ground state respectively. Let Λn\Lambda_n   be the wavelength of the emitted photon in the transition from the nthn^{th}   state to the ground state. For large nn  , (A, B are constants):

    • A.Λn2A+Bλn2\Lambda_n^2 \approx A + B\lambda_n^2
    • B.Λn2λn\Lambda_n^2 \approx \lambda_n
    • C.ΛnA+Bλn2\Lambda_n \approx A + \frac{B}{\lambda_n^2}Correct
    • D.ΛnA+Bλn\Lambda_n \approx A + B\lambda_n
  10. 10
    MCQ4 marks

    The reading of the ammeter for a silicon diode in the given circuit is:

    • A.11.5 mA11.5 \text{ mA}Correct
    • B.13.5 mA13.5 \text{ mA}
    • C.0
    • D.15 mA15 \text{ mA}
  11. 11
    MCQ4 marks

    An electron, a proton and an alpha particle having the same kinetic energy are moving in circular orbits of radii re,rp,rαr_e, r_p, r_\alpha   respectively in a uniform magnetic field B. The relation between re,rp,rαr_e, r_p, r_\alpha   is:

    • A.re<rp<rαr_e < r_p < r_\alpha
    • B.re<rα<rpr_e < r_\alpha < r_p
    • C.re>rp=rαr_e > r_p = r_\alpha
    • D.re<rp=rαr_e < r_p = r_\alphaCorrect
  12. 12
    MCQ4 marks

    A parallel plate capacitor of capacitance 90 pF90 \text{ pF}   is connected to a battery of emf 20 V20 \text{ V}  . If a dielectric material of dielectric constant K=5/3K = 5/3   is inserted between the plates, the magnitude of the induced charge will be:

    • A.2.4 nC2.4 \text{ nC}
    • B.0.9 nC0.9 \text{ nC}
    • C.1.2 nC1.2 \text{ nC}Correct
    • D.0.3 nC0.3 \text{ nC}
  13. 13
    MCQ4 marks

    For an RLC circuit driven with voltage of amplitude vmv_m   and frequency ω0=1LC\omega_0 = \frac{1}{\sqrt{LC}}   the current exhibits resonance. The quality factor, Q is given by:

    • A.R(ω0C)\frac{R}{(\omega_0 C)}
    • B.CRω0\frac{CR}{\omega_0}
    • C.ω0LR\frac{\omega_0 L}{R}Correct
    • D.ω0RL\frac{\omega_0 R}{L}
  14. 14
    MCQ4 marks

    A telephonic communication service is working at carrier frequency of 10 GHz10 \text{ GHz}  . Only 10%10\%   of it is utilized for transmission. How many telephonic channels can be transmitted simultaneously if each channel requires a bandwidth of 5 kHz5 \text{ kHz}  ?

    • A.2×1052 \times 10^5
    • B.2×1062 \times 10^6Correct
    • C.2×1032 \times 10^3
    • D.2×1042 \times 10^4
  15. 15
    MCQ4 marks

    A granite rod of 60 cm60 \text{ cm}   length is clamped at its middle point and is set into longitudinal vibrations. The density of granite is 2.7×103 kg/m32.7 \times 10^3 \text{ kg/m}^3   and its Young's modulus is 9.27×1010 Pa9.27 \times 10^{10} \text{ Pa}  . What will be the fundamental frequency of the longitudinal vibrations?

    • A.10 kHz10 \text{ kHz}
    • B.7.5 kHz7.5 \text{ kHz}
    • C.5 kHz5 \text{ kHz}Correct
    • D.2.5 kHz2.5 \text{ kHz}
  16. 16
    MCQ4 marks

    Seven identical circular planar disks, each of mass M and radius R are welded symmetrically as shown. The moment of inertia of the arrangement about the axis normal to the plane and passing through the point P is:

    • A.732MR2\frac{73}{2} MR^2
    • B.1812MR2\frac{181}{2} MR^2Correct
    • C.192MR2\frac{19}{2} MR^2
    • D.552MR2\frac{55}{2} MR^2
  17. 17
    MCQ4 marks

    Three concentric metal shells A, B and C of respective radii a, b and c (a<b<c)(a < b < c)   have surface charge densities +σ,σ+\sigma, -\sigma   and +σ+\sigma   respectively. The potential of shell B is:

    • A.σϵ0[b2c2b+a]\frac{\sigma}{\epsilon_0}\left[\frac{b^2 - c^2}{b} + a\right]
    • B.σϵ0[b2c2c+a]\frac{\sigma}{\epsilon_0}\left[\frac{b^2 - c^2}{c} + a\right]
    • C.σϵ0[a2b2a+c]\frac{\sigma}{\epsilon_0}\left[\frac{a^2 - b^2}{a} + c\right]
    • D.σϵ0[a2b2b+c]\frac{\sigma}{\epsilon_0}\left[\frac{a^2 - b^2}{b} + c\right]Correct
  18. 18
    MCQ4 marks

    In a potentiometer experiment, it is found that no current passes through the galvanometer when the terminals of the cell are connected across 52 cm52 \text{ cm}   of the potentiometer wire. If the cell is shunted by a resistance of 5Ω5 \, \Omega   a balance is found when the cell is connected across 40 cm40 \text{ cm}   of the wire. Find the internal resistance of the cell.

    • A.2Ω2 \, \Omega
    • B.2.5Ω2.5 \, \Omega
    • C.1Ω1 \, \Omega
    • D.1.5Ω1.5 \, \OmegaCorrect
  19. 19
    MCQ4 marks

    An EM wave from air enters a medium. The electric fields are E1=E01x^cos[2πν(zct)]\vec{E}_1 = E_{01}\hat{x}\cos \left[2\pi \nu \left(\frac{z}{c} -t\right)\right]   in air and E2=E02x^cos[k(2zct)]\vec{E}_2 = E_{02}\hat{x}\cos \left[k(2z - ct)\right]   in medium, where the wave number k and frequency ν\nu   refer to their values in air. The medium is non-magnetic. If ϵr1\epsilon_{r1}   and ϵr2\epsilon_{r2}   refer to relative permittivities of air and medium respectively, which of the following options is correct?

    • A.ϵr1ϵr2=14\frac{\epsilon_{r1}}{\epsilon_{r2}} = \frac{1}{4}Correct
    • B.ϵr1ϵr2=12\frac{\epsilon_{r1}}{\epsilon_{r2}} = \frac{1}{2}
    • C.ϵr1ϵr2=4\frac{\epsilon_{r1}}{\epsilon_{r2}} = 4
    • D.ϵr1ϵr2=2\frac{\epsilon_{r1}}{\epsilon_{r2}} = 2
  20. 20
    MCQ4 marks

    The angular width of the central maximum in a single slit diffraction pattern is 6060^\circ  . The width of the slit is 1μm1 \mu \text{m}  . The slit is illuminated by monochromatic plane waves. If another slit of same width is made near it, Young's fringes can be observed on a screen placed at a distance 50 cm50 \text{ cm}   from the slits. If the observed fringe width is 1 cm1 \text{ cm}  , what is slit separation distance? (i.e. distance between the centres of each slit.)

    • A.75μm75 \mu \text{m}
    • B.100μm100 \mu \text{m}
    • C.25μm25 \mu \text{m}Correct
    • D.50μm50 \mu \text{m}
  21. 21
    MCQ4 marks

    A silver atom in a solid oscillates in simple harmonic motion in some direction with a frequency of 1012/sec10^{12} \text{/sec}  . What is the force constant of the bonds connecting one atom with the other? (Mole wt. of silver = 108 and Avagadro number = 6.02×1023 gm mole16.02 \times 10^{23} \text{ gm mole}^{-1}  )

    • A.2.2 N/m2.2 \text{ N/m}
    • B.5.5 N/m5.5 \text{ N/m}
    • C.6.4 N/m6.4 \text{ N/m}
    • D.7.1 N/m7.1 \text{ N/m}Correct
  22. 22
    MCQ4 marks

    From a uniform circular disc of radius R and mass 9 M, a small disc of radius R/3R/3   is removed as shown in the figure. The moment of inertia of the remaining disc about an axis perpendicular to the plane of the disc and passing through centre of disc is:

    • A.10MR210 MR^2
    • B.379MR2\frac{37}{9} MR^2
    • C.4MR24 MR^2
    • D.409MR2\frac{40}{9} MR^2Correct
  23. 23
    MCQ4 marks

    In a collinear collision, a particle with an initial speed v0v_0   strikes a stationary particle of the same mass. If the final total kinetic energy is 50%50\%   greater than the original kinetic energy, the magnitude of the relative velocity between the two particles, after collision, is:

    • A.v0/2v_0 / 2
    • B.v0/2v_0 / \sqrt{2}
    • C.v0/4v_0 / 4
    • D.2v0\sqrt{2} v_0Correct
  24. 24
    MCQ4 marks

    The dipole moment of a circular loop carrying a current I, is m and the magnetic field at the centre of the loop is B1B_1  . When the dipole moment is doubled by keeping the current constant, the magnetic field at the centre of the loop is B2B_2  . The ratio B1/B2B_1/B_2   is:

    • A.2\sqrt{2}Correct
    • B.1/21/\sqrt{2}
    • C.2
    • D.3\sqrt{3}
  25. 25
    MCQ4 marks

    The density of a material in the shape of a cube is determined by measuring three sides of the cube and its mass. If the relative errors in measuring the mass and length are respectively 1.5%1.5\%   and 1%1\%  , the maximum error in determining the density is:

    • A.4.5%4.5\%Correct
    • B.6%6\%
    • C.2.5%2.5\%
    • D.3.5%3.5\%
  26. 26
    MCQ4 marks

    On interchanging the resistances, the balance point of a meter bridge shifts to the left by 10 cm10 \text{ cm}  . The resistance of their series combination is 1 kΩ1 \text{ k}\Omega  . How much was the resistance on the left slot before interchanging the resistances?

    • A.550Ω550 \, \OmegaCorrect
    • B.910Ω910 \, \Omega
    • C.990Ω990 \, \Omega
    • D.505Ω505 \, \Omega
  27. 27
    MCQ4 marks

    In an a.c. circuit, the instantaneous e.m.f. and current are given by e=100sin30te = 100 \sin 30 t   and i=20sin(30tπ/4)i = 20 \sin (30 t - \pi/4)  . In one cycle of a.c., the average power consumed by the circuit and the wattless current are, respectively:

    • A.50/2,050/\sqrt{2}, 0
    • B.50, 0
    • C.50, 10
    • D.1000/2,101000/\sqrt{2}, 10Correct
  28. 28
    MCQ4 marks

    All the graphs below are intended to represent the same motion. One of them does it incorrectly. Pick it up.

    • A.Graph of distance vs time
    • B.Graph of velocity vs timeCorrect
    • C.Graph of velocity vs position
    • D.Graph of position vs time
  29. 29
    MCQ4 marks

    Two moles of an ideal monoatomic gas occupies a volume V at 27C27^\circ\text{C}  . The gas expands adiabatically to a volume 2 V. Calculate (a) the final temperature of the gas and (b) change in its internal energy.

    • A.189 K189 \text{ K}   (b) 2.7 kJ-2.7 \text{ kJ}Correct
    • B.195 K195 \text{ K}   (b) 2.7 kJ2.7 \text{ kJ}
    • C.189 K189 \text{ K}   (b) 2.7 kJ2.7 \text{ kJ}
    • D.195 K195 \text{ K}   (b) 2.7 kJ-2.7 \text{ kJ}
  30. 30
    MCQ4 marks

    A particle is moving with a uniform speed in a circular orbit of radius R in a central force inversely proportional to the nth power of R. If the period of rotation of the particle is T, then:

    • A.TR(n+1)/2T \propto R^{(n + 1) / 2}Correct
    • B.TRn/2T \propto R^{n / 2}
    • C.TR3/2T \propto R^{3 / 2}   for any n.
    • D.TRn2+1T \propto R^{\frac{n}{2} + 1}
  31. 31
    MCQ4 marks

    If the tangent at (1, 7) to the curve x2=y6x^2 = y - 6   touches the circle x2+y2+16x+12y+c=0x^2 + y^2 + 16x + 12y + c = 0   then the value of cc   is:

    • A.85
    • B.95Correct
    • C.195
    • D.185
  32. 32
    MCQ4 marks

    If L1L_1   is the line of intersection of the planes 2x2y+3z2=02x - 2y + 3z - 2 = 0  , xy+z+1=0x - y + z + 1 = 0   and L2L_2   is the line of intersection of the planes x+2yz3=0x + 2y - z - 3 = 0  , 3xy+2z1=03x - y + 2z - 1 = 0  , then the distance of the origin from the plane, containing the lines L1L_1   and L2L_2  , is:

    • A.122\frac{1}{2\sqrt{2}}
    • B.12\frac{1}{\sqrt{2}}
    • C.142\frac{1}{4\sqrt{2}}
    • D.132\frac{1}{3\sqrt{2}}Correct
  33. 33
    MCQ4 marks

    If α,βC\alpha, \beta \in \mathbf{C}   are the distinct roots of the equation x2x+1=0x^2 - x + 1 = 0  , then α101+β107\alpha^{101} + \beta^{107}   is equal to:

    • A.1Correct
    • B.2
    • C.-1
    • D.0
  34. 34
    MCQ4 marks

    Tangents are drawn to the hyperbola 4x2y2=364x^2 - y^2 = 36   at the points PP   and QQ  . If these tangents intersect at the point T(0,3)T(0,3)   then the area (in sq. units) of ΔPTQ\Delta PTQ   is:

    • A.60360\sqrt{3}
    • B.36536\sqrt{5}
    • C.45545\sqrt{5}Correct
    • D.54354\sqrt{3}
  35. 35
    MCQ4 marks

    If the curves y2=6xy^2 = 6x  , 9x2+by2=169x^2 + by^2 = 16   intersect each other at right angles, then the value of bb   is:

    • A.4Correct
    • B.9/2
    • C.6
    • D.7/2
  36. 36
    MCQ4 marks

    If the system of linear equations x+ky+3z=0x + ky + 3z = 0  , 3x+ky2z=03x + ky - 2z = 0  , 2x+4y3z=02x + 4y - 3z = 0   has a non-zero solution (x,y,z)(x,y,z)  , then xzy2\frac{xz}{y^2}   is equal to:

    • A.-30
    • B.30
    • C.-10Correct
    • D.10
  37. 37
    MCQ4 marks

    Let S={xR:x0 and 2x3+x(x6)+6=0}S = \{x \in \mathbb{R} : x \geq 0 \text{ and } 2 | \sqrt{x} - 3 | + \sqrt{x} (\sqrt{x} - 6) + 6 = 0 \}  . Then S:

    • A.contains exactly two elements.Correct
    • B.contains exactly four elements.
    • C.is an empty set.
    • D.contains exactly one element.
  38. 38
    MCQ4 marks

    If sum of all the solutions of the equation 8cosx(cos(π6+x)cos(π6x)12)=18\cos x \cdot (\cos (\frac{\pi}{6} + x) \cdot \cos (\frac{\pi}{6} - x) - \frac{1}{2}) = 1   in [0,π][0, \pi]   is kπk\pi  , then kk   is equal to:

    • A.8/9
    • B.20/9
    • C.2/3
    • D.13/9Correct
  39. 39
    MCQ4 marks

    A bag contains 4 red and 6 black balls. A ball is drawn at random from the bag, its colour is observed and this ball along with two additional balls of the same colour are returned to the bag. If now a ball is drawn at random from the bag, then the probability that this drawn ball is red, is:

    • A.1/5
    • B.3/4
    • C.3/10
    • D.2/5Correct
  40. 40
    MCQ4 marks

    Let f(x)=x2+1x2f(x) = x^2 + \frac{1}{x^2}   and g(x)=x1xg(x) = x - \frac{1}{x}  , xR{1,0,1}x \in \mathbb{R} - \{-1, 0, 1\}  . If h(x)=f(x)/g(x)h(x) = f(x)/g(x)  , then the local minimum value of h(x)h(x)   is:

    • A.22-2\sqrt{2}
    • B.222\sqrt{2}Correct
    • C.3
    • D.-3
  41. 41
    MCQ4 marks

    Two sets A and B are as under: A={(a,b)R×R:a5<1 and b5<1}A = \{(a,b)\in \mathbf{R}\times \mathbf{R}:|a - 5| < 1 \text{ and } | b - 5 | < 1 \}  ; B={(a,b)R×R:4(a6)2+9(b5)236}B = \{(a, b) \in R \times R: 4 (a - 6)^2 + 9 (b - 5)^2 \leq 36 \}  . Then:

    • A.AB=ϕA \cap B = \phi
    • B.neither ABA \subset B   nor BAB \subset A
    • C.BAB \subset A
    • D.ABA \subset BCorrect
  42. 42
    MCQ4 marks

    The Boolean expression (pq)(pq)\sim (p \lor q) \lor (\sim p \land q)   is equivalent to:

    • A.q
    • B.q\sim q
    • C.p\sim pCorrect
    • D.p
  43. 43
    MCQ4 marks

    Tangent and normal are drawn at P(16,16)P(16,16)   on the parabola y2=16xy^2 = 16x   which intersect the axis of the parabola at A and B, respectively. If C is the centre of the circle through the points P, A and B and CPB=θ\angle CPB = \theta  , then a value of tanθ\tan \theta   is:

    • A.3
    • B.4/3
    • C.1/2
    • D.2Correct
  44. 44
    MCQ4 marks

    If x42x2x2xx42x2x2xx4=(A+Bx)(xA)2\left| \begin{array}{ccc}x - 4 & 2x & 2x\\ 2x & x - 4 & 2x\\ 2x & 2x & x - 4 \end{array} \right| = (A + Bx)(x - A)^2  , then the ordered pair (A,B)(A,B)   is equal to:

    • A.(-4, 5)Correct
    • B.(4, 5)
    • C.(-4, -5)
    • D.(-4, 3)
  45. 45
    MCQ4 marks

    The sum of the co-efficients of all odd degree terms in the expansion of (x+x31)5+(xx31)5,(x>1)(x + \sqrt{x^3 - 1})^5 + (x - \sqrt{x^3 - 1})^5, (x > 1)   is:

    • A.1
    • B.2Correct
    • C.-1
    • D.0
  46. 46
    MCQ4 marks

    Let a1,a2,a3,,a49a_1, a_2, a_3, \dots, a_{49}   be in A.P. such that k=012a4k+1=416\sum_{k=0}^{12} a_{4k+1} = 416   and a9+a43=66a_9 + a_{43} = 66  . If a12+a22++a172=140ma_1^2 + a_2^2 + \dots + a_{17}^2 = 140 m  , then m is equal to:

    • A.34Correct
    • B.33
    • C.66
    • D.68
  47. 47
    MCQ4 marks

    A straight line through a fixed point (2, 3) intersects the coordinate axes at distinct points PP   and QQ  . If OO   is the origin and the rectangle OPRQ is completed, then the locus of RR   is:

    • A.3x+2y=xy3x + 2y = xyCorrect
    • B.3x+2y=6xy3x + 2y = 6xy
    • C.3x+2y=63x + 2y = 6
    • D.2x+3y=xy2x + 3y = xy
  48. 48
    MCQ4 marks

    The value of π2π2sin2x1+2xdx\int_{-\frac{\pi}{2}}^{\frac{\pi}{2}}\frac{\sin^2x}{1 + 2^x}dx   is:

    • A.4π4\pi
    • B.π/4\pi/4Correct
    • C.π/8\pi/8
    • D.π/2\pi/2
  49. 49
    MCQ4 marks

    Let g(x)=cosx2g(x) = \cos x^2  , f(x)=xf(x) = \sqrt{x}  , and α,β(α<β)\alpha, \beta (\alpha < \beta)   be the roots of the quadratic equation 18x29πx+π2=018x^2 - 9\pi x + \pi^2 = 0  . Then the area (in sq. units) bounded by the curve y=(gf)(x)y = (g\circ f)(x)   and the lines x=α,x=βx = \alpha, x = \beta   and y=0y = 0  , is:

    • A.12(32)\frac{1}{2} (\sqrt{3} -\sqrt{2})
    • B.12(21)\frac{1}{2} (\sqrt{2} - 1)
    • C.12(31)\frac{1}{2} (\sqrt{3} - 1)Correct
    • D.12(3+1)\frac{1}{2} (\sqrt{3} + 1)
  50. 50
    MCQ4 marks

    For each tRt \in \mathbb{R}  , let [t] be the greatest integer less than or equal to tt  . Then limx0+x([1x]+[2x]++[15x])\lim_{x \to 0^+} x \left(\left[ \frac{1}{x} \right] + \left[ \frac{2}{x} \right] + \dots + \left[ \frac{15}{x} \right]\right)  :

    • A.is equal to 120.Correct
    • B.does not exist (in R\mathbf{R}   ).
    • C.is equal to 0.
    • D.is equal to 15.
  51. 51
    MCQ4 marks

    If i=19(xi5)=9\sum_{i=1}^{9}(x_i - 5) = 9   and i=19(xi5)2=45\sum_{i=1}^{9}(x_i - 5)^2 = 45  , then the standard deviation of the 9 items x1,x2,,x9x_1, x_2, \dots, x_9   is:

    • A.2Correct
    • B.3
    • C.9
    • D.4
  52. 52
    MCQ4 marks

    The integral sin2xcos2x(sin5x+cos3xsin2x+sin3xcos2x+cos5x)2dx\int \frac{\sin^2 x \cos^2 x}{(\sin^5 x + \cos^3 x \sin^2 x + \sin^3 x \cos^2 x + \cos^5 x)^2} dx   is equal to:

    • A.11+cot3x+C\frac{1}{1 + \cot^3 x} + C
    • B.11+cot3x+C\frac{-1}{1 + \cot^3 x} + C
    • C.13(1+tan3x)+C\frac{1}{3(1 + \tan^3 x)} + C
    • D.13(1+tan3x)+C\frac{-1}{3(1 + \tan^3x)} + CCorrect
  53. 53
    MCQ4 marks

    Let S={tR:f(x)=xπ(ex1)sinx is not differentiable at t}S = \{t \in \mathbf{R} : f(x) = |x - \pi| \cdot (e^{|x|} - 1) \sin |x| \text{ is not differentiable at } t \}  . Then the set S is equal to:

    • A.{π}\{\pi\}
    • B.{0,π}\{0, \pi\}
    • C.ϕ\phi   (an empty set)Correct
    • D.{0}\{0\}
  54. 54
    MCQ4 marks

    Let y=y(x)y = y(x)   be the solution of the differential equation sinxdydx+ycosx=4x,x(0,π)\sin x \frac{dy}{dx} + y \cos x = 4x, x \in (0, \pi)  . If y(π/2)=0y(\pi/2) = 0  , then y(π/6)y(\pi/6)   is equal to:

    • A.89π2-\frac{8}{9}\pi^2
    • B.49π2-\frac{4}{9}\pi^2
    • C.493π2\frac{4}{9\sqrt{3}}\pi^2
    • D.893π2\frac{-8}{9\sqrt{3}}\pi^2Correct
  55. 55
    MCQ4 marks

    Let u\vec{u}   be a vector coplanar with the vectors a=2i^+3j^k^\vec{a} = 2\hat{i} + 3\hat{j} - \hat{k}   and b=j^+k^\vec{b} = \hat{j} + \hat{k}  . If u\vec{u}   is perpendicular to a\vec{a}   and ub=24\vec{u} \cdot \vec{b} = 24  , then u2|\vec{u}|^2   is equal to:

    • A.256
    • B.84
    • C.336Correct
    • D.315
  56. 56
    MCQ4 marks

    The length of the projection of the line segment joining the points (5,1,4)(5, -1, 4)   and (4,1,3)(4, -1, 3)   on the plane, x+y+z=7x + y + z = 7   is:

    • A.1/3
    • B.2/3\sqrt{2/3}Correct
    • C.2/32/\sqrt{3}
    • D.2/3
  57. 57
    MCQ4 marks

    PQR is a triangular park with PQ=PR=200 mPQ = PR = 200 \text{ m}  . A T.V. tower stands at the mid-point of QR. If the angles of elevation of the top of the tower at P, Q and R are respectively 4545^\circ  , 3030^\circ   and 3030^\circ  , then the height of the tower (in m) is:

    • A.1003100\sqrt{3}
    • B.50250\sqrt{2}
    • C.100Correct
    • D.50
  58. 58
    MCQ4 marks

    From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary are to be selected and arranged in a row on a shelf so that the dictionary is always in the middle. The number of such arrangements is:

    • A.at least 500 but less than 750
    • B.at least 750 but less than 1000
    • C.at least 1000Correct
    • D.less than 500
  59. 59
    MCQ4 marks

    Let A be the sum of the first 20 terms and B be the sum of the first 40 terms of the series 12+222+32+242+52+262+1^2 + 2 \cdot 2^2 + 3^2 + 2 \cdot 4^2 + 5^2 + 2 \cdot 6^2 + \dots  . If B2A=100λB - 2A = 100\lambda  , then λ\lambda   is equal to:

    • A.464
    • B.496
    • C.232
    • D.248Correct
  60. 60
    MCQ4 marks

    Let the orthocentre and centroid of a triangle be A(3,5)A(-3, 5)   and B(3,3)B(3, 3)   respectively. If CC   is the circumcentre of this triangle, then the radius of the circle having line segment AC as diameter, is:

    • A.35/23\sqrt{5/2}Correct
    • B.352\frac{3\sqrt{5}}{2}
    • C.10\sqrt{10}
    • D.2102\sqrt{10}
  61. 61
    MCQ4 marks

    Total number of lone pair of electrons in I3I_3^-   ion is:

    • A.9Correct
    • B.12
    • C.3
    • D.6
  62. 62
    MCQ4 marks

    Which of the following salts is the most basic in aqueous solution?

    • A.FeCl3
    • B.Pb(CH3COO)2
    • C.Al(CN)3
    • D.CH3COOKCorrect
  63. 63
    MCQ4 marks

    Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A reacts with Br2Br_2   to form product B. A and B are respectively:

    • A.Product structures shown in Option 1
    • B.Product structures shown in Option 2
    • C.Product structures shown in Option 3Correct
    • D.Product structures shown in Option 4
  64. 64
    MCQ4 marks

    The increasing order of basicity of the following compounds is: (a) NH2NH_2   (b) Structure b (c) Structure c (d) NHCH3NHCH_3

    • A.< (a) < (d) < (c)Correct
    • B.< (b) < (a) < (c)
    • C.< (b) < (c) < (d)
    • D.< (a) < (c) < (d)
  65. 65
    MCQ4 marks

    An alkali is titrated against an acid with methyl orange as indicator, which of the following is a correct combination?

    • A.Base: Weak, Acid: Strong, End point: Yellow to pinkish redCorrect
    • B.Base: Strong, Acid: Strong, End point: Pink to colourless
    • C.Base: Weak, Acid: Strong, End point: Colourless to pink
    • D.Base: Strong, Acid: Strong, End point: Pinkish red to yellow
  66. 66
    MCQ4 marks

    The trans-alkenes are formed by the reduction of alkynes with:

    • A.Na/liq. NH3NH_3Correct
    • B.Sn-HCl
    • C.H2Pd/C,BaSO4H_2 - Pd/C, BaSO_4
    • D.NaBH4
  67. 67
    MCQ4 marks

    The ratio of mass percent of C and H of an organic compound (CxHyOz)(C_xH_yO_z)   is 6:1. If one molecule of the above compound (CxHyOz)(C_xH_yO_z)   contains half as much oxygen as required to burn one molecule of compound CxHyC_xH_y   completely to CO2CO_2   and H2OH_2O  . The empirical formula of compound CxHyOzC_xH_yO_z   is:

    • A.C3H4O2C_3H_4O_2
    • B.C2H4O3C_2H_4O_3Correct
    • C.C3H6O3C_3H_6O_3
    • D.C2H4OC_2H_4O
  68. 68
    MCQ4 marks

    Hydrogen peroxide oxidises [Fe(CN)6]4[Fe(CN)_6]^{4-}   to [Fe(CN)6]3[Fe(CN)_6]^{3-}   in acidic medium but reduces [Fe(CN)6]3[Fe(CN)_6]^{3-}   to [Fe(CN)6]4[Fe(CN)_6]^{4-}   in alkaline medium. The other products formed are, respectively:

    • A.H2OH_2O   and (H2O+O2)(H_2O + O_2)Correct
    • B.H2OH_2O   and (H2O+OH)(H_2O + OH^-)
    • C.(H2O+O2)(H_2O + O_2)   and H2OH_2O
    • D.(H2O+O2)(H_2O + O_2)   and (H2O+OH)(H_2O + OH^-)
  69. 69
    MCQ4 marks

    The major product formed in the following reaction is: [Reaction scheme provided with image]

    • A.Product structure 1
    • B.Product structure 2
    • C.Product structure 3
    • D.Product structure 4Correct
  70. 70
    MCQ4 marks

    How long (approximate) should water be electrolysed by passing through 100 amperes current so that the oxygen released can completely burn 27.66 g27.66 \text{ g}   of diborane? Atomic weight of B = 10.8u

    • A.2 hoursCorrect
    • B.6 hours
    • C.4 hours
    • D.8 hours
  71. 71
    MCQ4 marks

    Which of the following lines correctly show the temperature dependence of equilibrium constant, K, for an exothermic reaction?

    • A.C and D
    • B.A and D
    • C.A and B
    • D.B and CCorrect
  72. 72
    MCQ4 marks

    At 518C518^\circ\text{C}  , the rate of decomposition of a sample of gaseous acetaldehyde, initially at a pressure of 363 Torr, was 1.00 Torr s1s^{-1}   when 5%5\%   had reacted and 0.5 Torr s1s^{-1}   when 33%33\%   had reacted. The order of the reaction is:

    • A.1
    • B.0
    • C.2Correct
    • D.3
  73. 73
    MCQ4 marks

    Glucose on prolonged heating with HI gives:

    • A.Hexanoic acid
    • B.6-iodohexanal
    • C.n-HexaneCorrect
    • D.1-Hexene
  74. 74
    MCQ4 marks

    Consider the following reaction and statements: [Co(NH3)4Br2]++Br[Co(NH3)3Br3]+NH3[Co(NH_3)_4Br_2]^+ + Br^- \to [Co(NH_3)_3Br_3] + NH_3  . (I) Two isomers are produced if the reactant complex ion is a cis-isomer. (II) Two isomers are produced if the reactant complex ion is a trans-isomer. (III) Only one isomer is produced if the reactant complex ion is a trans-isomer. (IV) Only one isomer is produced if the reactant complex ion is a cis-isomer. The correct statements are:

    • A.and (IV)
    • B.and (IV)
    • C.and (II)
    • D.and (III)Correct
  75. 75
    MCQ4 marks

    The major product of the following reaction is: [Reaction scheme provided with image]

    • A.Product structure 1
    • B.Product structure 2
    • C.Product structure 3Correct
    • D.Product structure 4
  76. 76
    MCQ4 marks

    Phenol on treatment with CO2CO_2   in the presence of NaOH followed by acidification produces compound X as the major product. X on treatment with (CH3CO)2O(CH_3CO)_2O   in the presence of catalytic amount of H2SO4H_2SO_4   produces:

    • A.Product structure 1Correct
    • B.Product structure 2
    • C.Product structure 3
    • D.Product structure 4
  77. 77
    MCQ4 marks

    An aqueous solution contains an unknown concentration of Ba2+Ba^{2+}  . When 50 mL50 \text{ mL}   of a 1 M1 \text{ M}   solution of Na2SO4Na_2SO_4   is added, BaSO4BaSO_4   just begins to precipitate. The final volume is 500 mL500 \text{ mL}  . The solubility product of BaSO4BaSO_4   is 1×10101 \times 10^{-10}  . What is the original concentration of Ba2+Ba^{2+}  ?

    • A.1.1×109 M1.1 \times 10^{-9} \text{ M}Correct
    • B.1.0×1010 M1.0 \times 10^{-10} \text{ M}
    • C.5×109 M5 \times 10^{-9} \text{ M}
    • D.2×109 M2 \times 10^{-9} \text{ M}
  78. 78
    MCQ4 marks

    Which of the following compounds will be suitable for Kjeldahl's method for nitrogen estimation?

    • A.Structure 1
    • B.Structure 2
    • C.Structure 3
    • D.Structure 4Correct
  79. 79
    MCQ4 marks

    When metal MM'   is treated with NaOH, a white gelatinous precipitate XX'   is obtained, which is soluble in excess of NaOH. Compound XX'   when heated strongly gives an oxide which is used in chromatography as an adsorbent. The metal MM'   is:

    • A.AlCorrect
    • B.Fe
    • C.Zn
    • D.Ca
  80. 80
    MCQ4 marks

    An aqueous solution contains 0.10 M H2S0.10 \text{ M } H_2S   and 0.20 M HCl0.20 \text{ M } HCl  . If the equilibrium constants for the formation of HSHS^-   from H2SH_2S   is 1.0×1071.0 \times 10^{-7}   and that of S2S^{2-}   from HSHS^-   ions is 1.2×10131.2 \times 10^{-13}   then the concentration of S2S^{2-}   ions in aqueous solution is:

    • A.6×10216 \times 10^{-21}
    • B.5×10195 \times 10^{-19}
    • C.5×1085 \times 10^{-8}
    • D.3×10203 \times 10^{-20}Correct
  81. 81
    MCQ4 marks

    The recommended concentration of fluoride ion in drinking water is up to 1 ppm as fluoride ion is required to make teeth enamel harder by converting [3Ca3(PO4)2Ca(OH)2][3Ca_3(PO_4)_2 \cdot Ca(OH)_2]   to:

    • A.[3Ca3(PO4)2CaF2][3Ca_3(PO_4)_2 \cdot CaF_2]Correct
    • B.[3[Ca(OH)2]CaF2][3[Ca(OH)_2] \cdot CaF_2]
    • C.[CaF2][CaF_2]
    • D.[3(CaF2)Ca(OH)2][3(CaF_2) \cdot Ca(OH)_2]
  82. 82
    MCQ4 marks

    The compound that does not produce nitrogen gas by the thermal decomposition is:

    • A.NH4NO2
    • B.2SO4Correct
    • C.Ba(N3)2
    • D.2Cr2O7
  83. 83
    MCQ4 marks

    The predominant form of histamine present in human blood is (pKapK_a   Histidine = 6.0): [Structures provided in images]

    • A.Structure 1
    • B.Structure 2
    • C.Structure 3
    • D.Structure 4Correct
  84. 84
    MCQ4 marks

    The oxidation states of Cr in [Cr(H2O)6]Cl3[Cr(H_2O)_6]Cl_3  , [Cr(C6H6)2][Cr(C_6H_6)_2]  , and K2[Cr(CN)2(O)2(O2)(NH3)]K_2[Cr(CN)_2(O)_2(O_2)(NH_3)]   respectively are:

    • A.+3, 0, and +6Correct
    • B.+3, 0, and +4
    • C.+3, +4, and +6
    • D.+3, +2, and +4
  85. 85
    MCQ4 marks

    Which type of defect has the presence of cations in the interstitial sites?

    • A.Frenkel defectCorrect
    • B.Metal deficiency defect
    • C.Schottky defect
    • D.Vacancy defect
  86. 86
    MCQ4 marks

    The combustion of benzene (l) gives CO2(g)CO_2(g)   and H2O(l)H_2O(l)  . Given that heat of combustion of benzene at constant volume is 3263.9 kJ mol1-3263.9 \text{ kJ mol}^{-1}   at 25C25^\circ\text{C}  ; heat of combustion (in kJ mol1\text{kJ mol}^{-1}  ) of benzene at constant pressure will be: (R=8.314 J K1 mol1)(R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1})

    • A.3260
    • B.-3267.6Correct
    • C.6
    • D.-452.46
  87. 87
    MCQ4 marks

    Which of the following are Lewis acids?

    • A.PH3PH_3   and SiCl4SiCl_4
    • B.BCl3BCl_3   and AlCl3AlCl_3Correct
    • C.PH3PH_3   and BCl3BCl_3
    • D.AlCl3AlCl_3   and SiCl4SiCl_4
  88. 88
    MCQ4 marks

    Which of the following compounds contain(s) no covalent bond(s)? KCl,PH3,O2,B2H6,H2SO4KCl, PH_3, O_2, B_2H_6, H_2SO_4

    • A.KClCorrect
    • B.KCl, B2H6B_2H_6
    • C.KCl, B2H6,PH3B_2H_6, PH_3
    • D.KCl, H2SO4H_2SO_4
  89. 89
    MCQ4 marks

    For 1 molal aqueous solution of the following compounds, which one will show the highest freezing point?

    • A.[Co(H2O)4Cl2]Cl2H2O[Co(H_2O)_4Cl_2]Cl \cdot 2H_2O
    • B.[Co(H2O)3Cl3]3H2O[Co(H_2O)_3Cl_3] \cdot 3H_2OCorrect
    • C.[Co(H2O)6]Cl3[Co(H_2O)_6]Cl_3
    • D.[Co(H2O)5Cl]Cl2H2O[Co(H_2O)_5Cl]Cl_2 \cdot H_2O
  90. 90
    MCQ4 marks

    According to molecular orbital theory, which of the following will not be a viable molecule?

    • A.H2H_2^-
    • B.H22H_2^{2-}Correct
    • C.He22+He_2^{2+}
    • D.He2+He_2^+
  91. 91
    MCQ4 marks

    It is found that if a neutron suffers an elastic collinear collision with deuterium at rest, fractional loss of its energy is pdp_d  ; while for its similar collision with carbon nucleus at rest, fractional loss of energy is pcp_c  . The values of pdp_d   and pcp_c   are respectively:

    • A.(0, 0)
    • B.(0, 1)
    • C.(89, 28)Correct
    • D.(28, 89)
  92. 92
    MCQ4 marks

    The mass of a hydrogen molecule is 3.32×1027 kg3.32 \times 10^{-27} \text{ kg}  . If 102310^{23}   hydrogen molecules strike, per second, a fixed wall of area 2 cm22 \text{ cm}^2   at an angle of 4545^\circ   to the normal, and rebound elastically with a speed of 103 m/s10^3 \text{ m/s}  , then the pressure on the wall is nearly:

    • A.2.35×102 N/m22.35 \times 10^{2} \text{ N/m}^{2}
    • B.4.70×102 N/m24.70 \times 10^{2} \text{ N/m}^{2}
    • C.2.35×103 N/m22.35 \times 10^{3} \text{ N/m}^{2}Correct
    • D.4.70×103 N/m24.70 \times 10^{3} \text{ N/m}^{2}
  93. 93
    MCQ4 marks

    A solid sphere of radius rr   made of a soft material of bulk modulus KK   is surrounded by a liquid in a cylindrical container. A massless piston of area aa   floats on the surface of the liquid, covering entire cross section of cylindrical container. When a mass mm   is placed on the surface of the piston to compress the liquid, the fractional decrement in the radius of the sphere, (drr)\left(\frac{dr}{r}\right)  , is:

    • A.mg3Ka\frac{mg}{3Ka}Correct
    • B.mgKa\frac{mg}{Ka}
    • C.Kamg\frac{Ka}{mg}
    • D.Ka3mg\frac{Ka}{3mg}
  94. 94
    MCQ4 marks

    Two batteries with e.m.f. 12V12\text{V}   and 13V13\text{V}   are connected in parallel across a load resistor of 10Ω10\Omega  . The internal resistances of the two batteries are 1Ω1\Omega   and 2Ω2\Omega   respectively. The voltage across the load lies between:

    • A.11.4 V11.4\text{ V}   and 11.5 V11.5\text{ V}
    • B.11.7 V11.7\text{ V}   and 11.8 V11.8\text{ V}
    • C.11.6 V11.6\text{ V}   and 11.7 V11.7\text{ V}
    • D.11.5 V11.5\text{ V}   and 11.6 V11.6\text{ V}Correct
  95. 95
    MCQ4 marks

    A particle is moving in a circular path of radius aa   under the action of an attractive potential U=k2r2U = -\frac{k}{2r^2}  . Its total energy is:

    • A.ZeroCorrect
    • B.32ka2-\frac{3}{2}\frac{k}{a^2}
    • C.k4a2-\frac{k}{4a^2}
    • D.k2a2\frac{k}{2a^2}
  96. 96
    MCQ4 marks

    Two masses m1=5kgm_1 = 5\text{kg}   and m2=10kgm_2 = 10\text{kg}  , connected by an inextensible string over a frictionless pulley, are moving as shown in the figure. The coefficient of friction of horizontal surface is 0.15. The minimum weight mm   that should be put on top of m2m_2   to stop the motion is:

    • A.43.3kg43.3\text{kg}
    • B.10.3kg10.3\text{kg}
    • C.18.3kg18.3\text{kg}
    • D.27.3kg27.3\text{kg}Correct
  97. 97
    MCQ4 marks

    If the series limit frequency of the Lyman series is νL\nu_{L}   then the series limit frequency of the Pfund series is:

    • A.νL/16\nu_{L} / 16
    • B.νL/25\nu_{L} / 25Correct
    • C.25νL25\nu_{L}
    • D.16νL16\nu_{L}
  98. 98
    MCQ4 marks

    Unpolarized light of intensity II   passes through an ideal polarizer A. Another identical polarizer B is placed behind A. The intensity of light beyond B is found to be 12I\frac{1}{2}I   (initial state). Now another identical polarizer C is placed between A and B. The intensity beyond B is now found to be 18I\frac{1}{8}I  . The angle between polarizer A and C is:

    • A.4545^{\circ}Correct
    • B.6060^{\circ}
    • C.00^{\circ}
    • D.3030^{\circ}
  99. 99
    MCQ4 marks

    An electron from various excited states of hydrogen atom emit radiation to come to the ground state. Let λn,λg\lambda_{n}, \lambda_{g}   be the de Broglie wavelength of the electron in the nthn^{th}   state and the ground state respectively. Let Λn\Lambda_{n}   be the wavelength of the emitted photon in the transition from the nthn^{th}   state to the ground state. For large nn  , (A, B are constants)

    • A.Λn2A+Bλn2\Lambda_{n}^{2} \approx A + B\lambda_{n}^{2}
    • B.Λn2λ\Lambda_{n}^{2} \approx \lambda
    • C.ΛnA+Bλn2\Lambda_{n} \approx A + \frac{B}{\lambda_{n}^{2}}Correct
    • D.ΛnA+Bλn\Lambda_{n} \approx A + B\lambda_{n}
  100. 100
    MCQ4 marks

    The reading of the ammeter for a silicon diode in the given circuit is:

    • A.11.5 mA11.5\text{ mA}Correct
    • B.13.5 mA13.5\text{ mA}
    • C.0
    • D.15 mA15\text{ mA}
  101. 101
    MCQ4 marks

    An electron, a proton and an alpha particle having the same kinetic energy are moving in circular orbits of radii re,rp,rαr_e, r_p, r_\alpha   respectively in a uniform magnetic field B. The relation between re,rp,rαr_e, r_p, r_\alpha   is:

    • A.re<rp<rαr_e < r_p < r_\alpha
    • B.re<rα<rpr_e < r_\alpha < r_p
    • C.re>rp=rαr_e > r_p = r_\alpha
    • D.re<rp=rαr_e < r_p = r_\alphaCorrect
  102. 102
    MCQ4 marks

    A parallel plate capacitor of capacitance 90 pF90\text{ pF}   is connected to a battery of emf 20V20\text{V}  . If a dielectric material of dielectric constant K=53K = \frac{5}{3}   is inserted between the plates, the magnitude of the induced charge will be:

    • A.2.4 nC2.4\text{ nC}
    • B.0.9 nC0.9\text{ nC}
    • C.1.2 nC1.2\text{ nC}Correct
    • D.0.3 nC0.3\text{ nC}
  103. 103
    MCQ4 marks

    For an RLC circuit driven with voltage of amplitude vmv_{m}   and frequency ω0=1LC\omega_0 = \frac{1}{\sqrt{LC}}   the current exhibits resonance. The quality factor, Q is given by:

    • A.R(ω0C)\frac{R}{(\omega_0C)}
    • B.CRCR
    • C.ω0LR\frac{\omega_0 L}{R}Correct
    • D.ω0RL\frac{\omega_0 R}{L}
  104. 104
    MCQ4 marks

    A telephonic communication service is working at carrier frequency of 10 GHz10\text{ GHz}  . Only 10%10\%   of it is utilized for transmission. How many telephonic channels can be transmitted simultaneously if each channel requires a bandwidth of 5 kHz5\text{ kHz}  ?

    • A.2×1052 \times 10^{5}Correct
    • B.2×1062 \times 10^{6}
    • C.2×1032 \times 10^{3}
    • D.2×1042 \times 10^{4}
  105. 105
    MCQ4 marks

    A granite rod of 60 cm60\text{ cm}   length is clamped at its middle point and is set into longitudinal vibrations. The density of granite is 2.7×103 kg/m32.7 \times 10^{3}\text{ kg/m}^{3}   and its Young's modulus is 9.27×1010 Pa9.27 \times 10^{10}\text{ Pa}  . What will be the fundamental frequency of the longitudinal vibrations?

    • A.10 kHz10\text{ kHz}
    • B.7.5 kHz7.5\text{ kHz}
    • C.5 kHz5\text{ kHz}Correct
    • D.2.5 kHz2.5\text{ kHz}
  106. 106
    MCQ4 marks

    Seven identical circular planar disks, each of mass M and radius R are welded symmetrically as shown. The moment of inertia of the arrangement about the axis normal to the plane and passing through the point P is:

    • A.732MR2\frac{73}{2} MR^{2}
    • B.1812MR2\frac{181}{2} MR^{2}Correct
    • C.192MR2\frac{19}{2} MR^{2}
    • D.552MR2\frac{55}{2} MR^{2}
  107. 107
    MCQ4 marks

    Three concentric metal shells A, B and C of respective radii a,ba, b   and cc   (a<b<c)(a < b < c)   have surface charge densities +σ,σ+\sigma, -\sigma   and +σ+\sigma   respectively. The potential of shell B is:

    • A.σϵ0[b2c2b+a]\frac{\sigma}{\epsilon_0}\left[\frac{b^2 - c^2}{b} + a\right]
    • B.σϵ0[b2c2c+a]\frac{\sigma}{\epsilon_0}\left[\frac{b^2 - c^2}{c} + a\right]
    • C.σϵ0[a2b2a+c]\frac{\sigma}{\epsilon_0}\left[\frac{a^2 - b^2}{a} + c\right]
    • D.σϵ0[a2b2b+c]\frac{\sigma}{\epsilon_0}\left[\frac{a^2 - b^2}{b} + c\right]Correct
  108. 108
    MCQ4 marks

    In a potentiometer experiment, it is found that no current passes through the galvanometer when the terminals of the cell are connected across 52 cm52\text{ cm}   of the potentiometer wire. If the cell is shunted by a resistance of 5Ω5\Omega   a balance is found when the cell is connected across 40 cm40\text{ cm}   of the wire. Find the internal resistance of the cell.

    • A.2Ω2\Omega
    • B.2.5Ω2.5\Omega
    • C.1Ω1\Omega
    • D.1.5Ω1.5\OmegaCorrect
  109. 109
    MCQ4 marks

    An EM wave from air enters a medium. The electric fields are E1=E01x^cos[2πν(zct)]\vec{E}_1 = E_{01}\hat{x}\cos [2\pi \nu (\frac{z}{c} -t)]   in air and E2=E02x^cos[k(2zct)]\vec{E}_2 = E_{02}\hat{x}\cos [k(2z - ct)]   in medium, where the wave number kk   and frequency ν\nu   refer to their values in air. The medium is non-magnetic. If ϵr1\epsilon_{r1}   and ϵr2\epsilon_{r2}   refer to relative permittivities of air and medium respectively, which of the following options is correct?

    • A.ϵr1ϵr2=14\frac{\epsilon_{r1}}{\epsilon_{r2}} = \frac{1}{4}Correct
    • B.ϵr1ϵr2=12\frac{\epsilon_{r1}}{\epsilon_{r2}} = \frac{1}{2}
    • C.ϵr1ϵr2=4\frac{\epsilon_{r1}}{\epsilon_{r2}} = 4
    • D.ϵr1ϵr2=2\frac{\epsilon_{r1}}{\epsilon_{r2}} = 2
  110. 110
    MCQ4 marks

    The angular width of the central maximum in a single slit diffraction pattern is 6060^{\circ}  . The width of the slit is 1μm1\mu \text{m}  . The slit is illuminated by monochromatic plane waves. If another slit of same width is made near it, Young's fringes can be observed on a screen placed at a distance 50 cm50\text{ cm}   from the slits. If the observed fringe width is 1 cm1\text{ cm}  , what is slit separation distance? (i.e. distance between the centres of each slit.)

    • A.75μm75\mu \text{m}
    • B.100μm100\mu \text{m}
    • C.25μm25\mu \text{m}Correct
    • D.50μm50\mu \text{m}
  111. 111
    MCQ4 marks

    A silver atom in a solid oscillates in simple harmonic motion in some direction with a frequency of 1012/sec10^{12} / \text{sec}  . What is the force constant of the bonds connecting one atom with the other? (Mole wt. of silver = 108 and Avogadro number = 6.02×1023 g/mole6.02 \times 10^{23} \text{ g/mole}  )

    • A.2.2 N/m2.2\text{ N/m}
    • B.5.5 N/m5.5\text{ N/m}
    • C.6.4 N/m6.4\text{ N/m}
    • D.7.1 N/m7.1\text{ N/m}Correct
  112. 112
    MCQ4 marks

    From a uniform circular disc of radius R and mass 9 M, a small disc of radius R/3R/3   is removed as shown in the figure. The moment of inertia of the remaining disc about an axis perpendicular to the plane of the disc and passing through centre of disc is:

    • A.10MR210MR^2
    • B.379MR2\frac{37}{9} MR^2
    • C.4MR24MR^2Correct
    • D.409MR2\frac{40}{9} MR^2
  113. 113
    MCQ4 marks

    In a collinear collision, a particle with an initial speed v0v_{0}   strikes a stationary particle of the same mass. If the final total kinetic energy is 50% greater than the original kinetic energy, the magnitude of the relative velocity between the two particles, after collision, is:

    • A.v02\frac{v_{0}}{2}
    • B.v02\frac{v_{0}}{\sqrt{2}}
    • C.v04\frac{v_{0}}{4}
    • D.2v0\sqrt{2} v_{0}Correct
  114. 114
    MCQ4 marks

    The dipole moment of a circular loop carrying a current I, is mm   and the magnetic field at the centre of the loop is B1B_1  . When the dipole moment is doubled by keeping the current constant, the magnetic field at the centre of the loop is B2B_2  . The ratio B1/B2B_1/B_2   is:

    • A.2\sqrt{2}Correct
    • B.12\frac{1}{\sqrt{2}}
    • C.22
    • D.3\sqrt{3}
  115. 115
    MCQ4 marks

    The density of a material in the shape of a cube is determined by measuring three sides of the cube and its mass. If the relative errors in measuring the mass and length are respectively 1.5%1.5\%   and 1%1\%  , the maximum error in determining the density is:

    • A.4.5%4.5\%Correct
    • B.6%6\%
    • C.2.5%2.5\%
    • D.3.5%3.5\%
  116. 116
    MCQ4 marks

    On interchanging the resistances, the balance point of a meter bridge shifts to the left by 10 cm10\text{ cm}  . The resistance of their series combination is 1 kΩ1\text{ k}\Omega  . How much was the resistance on the left slot before interchanging the resistances?

    • A.550Ω550\OmegaCorrect
    • B.910Ω910\Omega
    • C.990Ω990\Omega
    • D.505Ω505\Omega
  117. 117
    MCQ4 marks

    In an a.c. circuit, the instantaneous e.m.f. and current are given by e=100sin30te = 100 \sin 30 t  , i=20sin(30tπ/4)i = 20 \sin (30t - \pi/4)  . In one cycle of a.c., the average power consumed by the circuit and the wattless current are, respectively:

    • A.502,0\frac{50}{\sqrt{2}}, 0
    • B.50,050, 0
    • C.50,1050, 10
    • D.10002,10\frac{1000}{\sqrt{2}}, 10Correct
  118. 118
    MCQ4 marks

    All the graphs below are intended to represent the same motion. One of them does it incorrectly. Pick it up.

    • A.Image (a) showing distance-time
    • B.Image (b) showing velocity-timeCorrect
    • C.Image (c) showing displacement-time
    • D.Image (d) showing velocity-displacement
  119. 119
    MCQ4 marks

    Two moles of an ideal monoatomic gas occupies a volume V at 27C27^{\circ}\text{C}  . The gas expands adiabatically to a volume 2 V. Calculate (a) the final temperature of the gas and (b) change in its internal energy.

    • A.189K189\text{K}   (b) 2.7kJ-2.7\text{kJ}Correct
    • B.195K195\text{K}   (b) 2.7kJ2.7\text{kJ}
    • C.189K189\text{K}   (b) 2.7kJ2.7\text{kJ}
    • D.195K195\text{K}   (b) 2.7kJ-2.7\text{kJ}
  120. 120
    MCQ4 marks

    A particle is moving with a uniform speed in a circular orbit of radius R in a central force inversely proportional to the nth power of R. If the period of rotation of the particle is T, then:

    • A.TR(n+1)/2T \propto R^{(n + 1) / 2}Correct
    • B.TRn/2T \propto R^{n / 2}
    • C.TR3/2T \propto R^{3 / 2}   for any n.
    • D.TRn2+1T \propto R^{\frac{n}{2} + 1}
  121. 121
    MCQ4 marks

    If the tangent at (1, 7) to the curve x2=y6x^{2} = y - 6   touches the circle x2+y2+16x+12y+c=0x^{2} + y^{2} + 16x + 12y + c = 0   then the value of cc   is:

    • A.85
    • B.95Correct
    • C.195
    • D.185
  122. 122
    MCQ4 marks

    If L1L_1   is the line of intersection of the planes 2x2y+3z2=02x - 2y + 3z - 2 = 0  , xy+z+1=0x - y + z + 1 = 0   and L2L_2   is the line of intersection of the planes x+2yz3=0x + 2y - z - 3 = 0  , 3xy+2z1=03x - y + 2z - 1 = 0  , then the distance of the origin from the plane, containing the lines L1L_1   and L2L_2  , is:

    • A.122\frac{1}{2\sqrt{2}}
    • B.12\frac{1}{\sqrt{2}}
    • C.142\frac{1}{4\sqrt{2}}
    • D.132\frac{1}{3\sqrt{2}}Correct
  123. 123
    MCQ4 marks

    If α,βC\alpha, \beta \in \mathbf{C}   are the distinct roots, of the equation x2x+1=0x^{2} - x + 1 = 0  , then α101+β107\alpha^{101} + \beta^{107}   is equal to:

    • A.1Correct
    • B.2
    • C.-1
    • D.0
  124. 124
    MCQ4 marks

    Tangents are drawn to the hyperbola 4x2y2=364x^{2} - y^{2} = 36   at the points PP   and QQ  . If these tangents intersect at the point T(0,3)T(0,3)   then the area (in sq. units) of ΔPTQ\Delta PTQ   is:

    • A.60360\sqrt{3}
    • B.36536\sqrt{5}
    • C.45545\sqrt{5}Correct
    • D.54354\sqrt{3}
  125. 125
    MCQ4 marks

    If the curves y2=6xy^{2} = 6x  , 9x2+by2=169x^{2} + by^{2} = 16   intersect each other at right angles, then the value of bb   is:

    • A.4Correct
    • B.92\frac{9}{2}
    • C.6
    • D.72\frac{7}{2}
  126. 126
    MCQ4 marks

    If the system of linear equations x+ky+3z=0x + ky + 3z = 0  , 3x+ky2z=03x + ky - 2z = 0  , 2x+4y3z=02x + 4y - 3z = 0   has a non-zero solution (x,y,z)(x,y,z)  , then xzy2\frac{xz}{y^2}   is equal to:

    • A.-30
    • B.30
    • C.-10
    • D.10Correct
  127. 127
    MCQ4 marks

    Let S={xR:x0 and 2x3+x(x6)+6=0}S = \{x \in \mathbb{R} : x \geq 0 \text{ and } 2 | \sqrt{x} - 3 | + \sqrt{x} (\sqrt{x} - 6) + 6 = 0 \}  . Then S:

    • A.contains exactly two elements.Correct
    • B.contains exactly four elements.
    • C.is an empty set.
    • D.contains exactly one element.
  128. 128
    MCQ4 marks

    If sum of all the solutions of the equation 8cosx(cos(π6+x)cos(π6x)12)=18\cos x \cdot (\cos (\frac{\pi}{6} + x) \cdot \cos (\frac{\pi}{6} - x) - \frac{1}{2}) = 1   in [0,π][0, \pi]   is kπk\pi  , then kk   is equal to:

    • A.\frac{8}{9}
    • B.\frac{20}{9}
    • C.\frac{2}{3}
    • D.\frac{13}{9}Correct
  129. 129
    MCQ4 marks

    A bag contains 4 red and 6 black balls. A ball is drawn at random from the bag, its colour is observed and this ball along with two additional balls of the same colour are returned to the bag. If now a ball is drawn at random from the bag, then the probability that this drawn ball is red, is:

    • A.\frac{1}{5}
    • B.\frac{3}{4}
    • C.\frac{3}{10}
    • D.\frac{2}{5}Correct
  130. 130
    MCQ4 marks

    Let f(x)=x2+1x2f(x) = x^{2} + \frac{1}{x^{2}}   and g(x)=x1xg(x) = x - \frac{1}{x}  , xR{1,0,1}x \in \mathbb{R} - \{-1, 0, 1\}  . If h(x)=f(x)g(x)h(x) = \frac{f(x)}{g(x)}  , then the local minimum value of h(x)h(x)   is:

    • A.22-2\sqrt{2}
    • B.222\sqrt{2}Correct
    • C.3
    • D.-3
  131. 131
    MCQ4 marks

    Two sets A and B are as under: A={(a,b)R×R:a5<1 and b5<1}A = \{(a,b)\in \mathbf{R}\times \mathbf{R}:|a - 5| < 1 \text{ and } |b - 5| < 1 \}  ; B={(a,b)R×R:4(a6)2+9(b5)236}B = \{(a, b) \in R \times R: 4 (a - 6) ^{2} + 9 (b - 5) ^{2} \leq 36 \}  . Then:

    • A.AB=ϕA \cap B = \phi
    • B.neither ABA \subset B   nor BAB \subset A
    • C.BAB \subset A
    • D.ABA \subset BCorrect
  132. 132
    MCQ4 marks

    The Boolean expression (pq)(pq)\sim (p \lor q) \lor (\sim p \land q)   is equivalent to:

    • A.q
    • B.q\sim q
    • C.p\sim pCorrect
    • D.p
  133. 133
    MCQ4 marks

    Tangent and normal are drawn at P(16,16)P(16,16)   on the parabola y2=16xy^{2} = 16x   which intersect the axis of the parabola at A and B, respectively. If C is the centre of the circle through the points P, A and B and CPB=θ\angle CPB = \theta  , then a value of tanθ\tan \theta   is:

    • A.3
    • B.\frac{4}{3}
    • C.\frac{1}{2}
    • D.2Correct
  134. 134
    MCQ4 marks

    If x42x2x2xx42x2x2xx4=(A+Bx)(xA)2,\begin{vmatrix}x - 4 & 2x & 2x\\ 2x & x - 4 & 2x\\ 2x & 2x & x - 4 \end{vmatrix} = (A + Bx)(x - A)^2,   then the ordered pair (A,B)(A, B)   is equal to:

    • A.(-4, 5)Correct
    • B.(4, 5)
    • C.(-4, -5)
    • D.(-4, 3)
  135. 135
    MCQ4 marks

    The sum of the co-efficients of all odd degree terms in the expansion of (x+x31)5+(xx31)5(x + \sqrt{x^{3} - 1})^{5} + (x - \sqrt{x^{3} - 1})^{5}  , (x>1)(x > 1)   is:

    • A.1
    • B.2Correct
    • C.-1
    • D.0
  136. 136
    MCQ4 marks

    Let a1,a2,a3,,a49a_1, a_2, a_3, \dots, a_{49}   be in A.P. such that k=012a4k+1=416\sum_{k=0}^{12} a_{4k+1} = 416   and a9+a43=66a_9 + a_{43} = 66  . If a12+a22++a172=140ma_1^2 + a_2^2 + \dots + a_{17}^2 = 140 m  , then m is equal to:

    • A.34Correct
    • B.33
    • C.66
    • D.68
  137. 137
    MCQ4 marks

    A straight line through a fixed point (2, 3) intersects the coordinate axes at distinct points PP   and QQ  . If OO   is the origin and the rectangle OPRQ is completed, then the locus of RR   is:

    • A.3x+2y=xy3x + 2y = xyCorrect
    • B.3x+2y=6xy3x + 2y = 6xy
    • C.3x+2y=63x + 2y = 6
    • D.2x+3y=xy2x + 3y = xy
  138. 138
    MCQ4 marks

    The value of π2π2sin2x1+2xdx\int_{-\frac{\pi}{2}}^{\frac{\pi}{2}} \frac{\sin^2x}{1 + 2^x}dx   is:

    • A.4\pi
    • B.\frac{\pi}{4}Correct
    • C.\frac{\pi}{8}
    • D.\frac{\pi}{2}
  139. 139
    MCQ4 marks

    Let g(x)=cosx2g(x) = \cos x^2  , f(x)=xf(x) = \sqrt{x}  , and α,β(α<β)\alpha, \beta (\alpha < \beta)   be the roots of the quadratic equation 18x29πx+π2=018x^2 - 9\pi x + \pi^2 = 0  . Then the area (in sq. units) bounded by the curve y=(gf)(x)y = (g\circ f)(x)   and the lines x=α,x=βx = \alpha, x = \beta   and y=0y = 0  , is:

    • A.\frac{1}{2} (\sqrt{3} - \sqrt{2})
    • B.\frac{1}{2} (\sqrt{2} - 1)
    • C.\frac{1}{2} (\sqrt{3} - 1)Correct
    • D.\frac{1}{2} (\sqrt{3} + 1)
  140. 140
    MCQ4 marks

    For each tRt \in \mathbb{R}  , let [t] be the greatest integer less than or equal to tt  . Then limx0+x([1x]+[2x]++[15x])\lim_{x \to 0^+} x ([\frac{1}{x}] + [\frac{2}{x}] + \dots + [\frac{15}{x}])  :

    • A.is equal to 120.Correct
    • B.does not exist.
    • C.is equal to 0.
    • D.is equal to 15.
  141. 141
    MCQ4 marks

    If i=19(xi5)=9\sum_{i=1}^{9}(x_i - 5) = 9   and i=19(xi5)2=45\sum_{i=1}^{9}(x_i - 5)^2 = 45  , then the standard deviation of the 9 items x1,x2,,x9x_1, x_2, \dots, x_9   is:

    • A.2Correct
    • B.3
    • C.9
    • D.4
  142. 142
    MCQ4 marks

    The integral sin2xcos2x(sin5x+cos3xsin2x+sin3xcos2x+cos5x)2dx\int \frac{\sin^{2} x \cos^{2} x}{(\sin^{5} x + \cos^{3} x \sin^{2} x + \sin^{3} x \cos^{2} x + \cos^{5} x)^{2}} dx   is equal to:

    • A.11+cot3x+C\frac{1}{1 + \cot^3 x} + C
    • B.11+cot3x+C\frac{-1}{1 + \cot^3 x} + C
    • C.13(1+tan3x)+C\frac{1}{3(1 + \tan^3 x)} + C
    • D.13(1+tan3x)+C\frac{-1}{3(1 + \tan^3 x)} + CCorrect
  143. 143
    MCQ4 marks

    Let S={tR:f(x)=xπ(ex1)sinx is not differentiable at t}S = \{t \in \mathbf{R} : f(x) = |x - \pi| \cdot (e^{|x|} - 1) \sin |x| \text{ is not differentiable at } t \}  . Then the set S is equal to:

    • A.\{\pi\}
    • B.\{0, \pi\}
    • C.\phi \text{ (an empty set)}Correct
    • D.\{0\}
  144. 144
    MCQ4 marks

    Let y=y(x)y = y(x)   be the solution of the differential equation sinxdydx+ycosx=4x,x(0,π)\sin x \frac{dy}{dx} + y \cos x = 4x, x \in (0, \pi)  . If y(π/2)=0y(\pi/2) = 0  , then y(π/6)y(\pi/6)   is equal to:

    • A.89π2-\frac{8}{9}\pi^2
    • B.49π2-\frac{4}{9}\pi^2
    • C.493π2\frac{4}{9\sqrt{3}}\pi^2
    • D.893π2\frac{-8}{9\sqrt{3}}\pi^2Correct
  145. 145
    MCQ4 marks

    Let u\vec{u}   be a vector coplanar with the vectors a=2i^+3j^k^\vec{a} = 2\hat{i} +3\hat{j} -\hat{k}   and b=j^+k^\vec{b} = \hat{j} +\hat{k}  . If u\vec{u}   is perpendicular to a\vec{a}   and ub=24\vec{u}\cdot \vec{b} = 24  , then u2|\vec{u}|^2   is equal to:

    • A.256
    • B.84
    • C.336
    • D.315Correct
  146. 146
    MCQ4 marks

    The length of the projection of the line segment joining the points (5, -1, 4) and (4, -1, 3) on the plane, x+y+z=7x + y + z = 7   is:

    • A.\frac{1}{3}
    • B.\sqrt{\frac{2}{3}}Correct
    • C.\frac{2}{\sqrt{3}}
    • D.\frac{2}{3}
  147. 147
    MCQ4 marks

    PQR is a triangular park with PQ=PR=200mPQ = PR = 200\text{m}  . A T.V. tower stands at the mid-point of QR. If the angles of elevation of the top of the tower at P, Q and R are respectively 45,3045^{\circ}, 30^{\circ}   and 3030^{\circ}  , then the height of the tower (in m) is:

    • A.1003100\sqrt{3}
    • B.50250\sqrt{2}
    • C.100Correct
    • D.50
  148. 148
    MCQ4 marks

    From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary are to be selected and arranged in a row on a shelf so that the dictionary is always in the middle. The number of such arrangements is:

    • A.at least 500 but less than 750
    • B.at least 750 but less than 1000
    • C.at least 1000Correct
    • D.less than 500
  149. 149
    MCQ4 marks

    Let A be the sum of the first 20 terms and B be the sum of the first 40 terms of the series 12+222+32+242+52+262+1^{2} + 2 \cdot 2^{2} + 3^{2} + 2 \cdot 4^{2} + 5^{2} + 2 \cdot 6^{2} + \dots  . If B2A=100λB - 2A = 100\lambda  , then λ\lambda   is equal to:

    • A.464
    • B.496
    • C.232
    • D.248Correct
  150. 150
    MCQ4 marks

    Let the orthocentre and centroid of a triangle be A(3,5)A(-3, 5)   and B(3,3)B(3, 3)   respectively. If C is the circumcentre of this triangle, then the radius of the circle having line segment AC as diameter, is:

    • A.3523\sqrt{\frac{5}{2}}Correct
    • B.352\frac{3\sqrt{5}}{2}
    • C.10\sqrt{10}
    • D.2102\sqrt{10}
  151. 151
    MCQ4 marks

    Total number of lone pair of electrons in I3I_3^-   ion is:

    • A.9Correct
    • B.12
    • C.3
    • D.6
  152. 152
    MCQ4 marks

    Which of the following salts is the most basic in aqueous solution?

    • A.FeCl3FeCl_3
    • B.Pb(CH3COO)2Pb(CH_3COO)_2
    • C.Al(CN)3Al(CN)_3
    • D.CH3COOKCH_3COOKCorrect
  153. 153
    MCQ4 marks

    Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A reacts with Br2Br_2   to form product B. A and B are respectively:

    • A.Option 1 based on image
    • B.Option 2 based on image
    • C.Option 3 based on imageCorrect
    • D.Option 4 based on image
  154. 154
    MCQ4 marks

    The increasing order of basicity of the following compounds is: (a) NH2NH_2  , (b) compound in image, (c) compound in image, (d) NHCH3NHCH_3

    • A.< (a) < (d) < (c)Correct
    • B.< (b) < (a) < (c)
    • C.< (b) < (c) < (d)
    • D.< (a) < (c) < (d)
  155. 155
    MCQ4 marks

    An alkali is titrated against an acid with methyl orange as indicator, which of the following is a correct combination?

    • A.Base: Weak, Acid: Strong, End point: Yellow to pinkish redCorrect
    • B.Base: Strong, Acid: Strong, End point: Pink to colourless
    • C.Base: Weak, Acid: Strong, End point: Colourless to pink
    • D.Base: Strong, Acid: Strong, End point: Pinkish red to yellow
  156. 156
    MCQ4 marks

    The trans-alkenes are formed by the reduction of alkynes with:

    • A.Na/liq.NH3Na/liq. NH_3Correct
    • B.SnHClSn-HCl
    • C.H2Pd/C,BaSO4H_2 - Pd/C, BaSO_4
    • D.NaBH4NaBH_4
  157. 157
    MCQ4 marks

    The ratio of mass percent of C and H of an organic compound (CxHyOzC_xH_yO_z  ) is 6:16:1  . If one molecule of the above compound (CxHyOzC_xH_yO_z  ) contains half as much oxygen as required to burn one molecule of compound CxHyC_xH_y   completely to CO2CO_2   and H2OH_2O  . The empirical formula of compound CxHyOzC_xH_yO_z   is:

    • A.C3H4O2C_3H_4O_2
    • B.C2H4O3C_2H_4O_3Correct
    • C.C3H6O3C_3H_6O_3
    • D.C2H4OC_2H_4O
  158. 158
    MCQ4 marks

    Hydrogen peroxide oxidises [Fe(CN)6]4[Fe(CN)_{6}]^{4-}   to [Fe(CN)6]3[Fe(CN)_{6}]^{3-}   in acidic medium but reduces [Fe(CN)6]3[Fe(CN)_{6}]^{3-}   to [Fe(CN)6]4[Fe(CN)_{6}]^{4-}   in alkaline medium. The other products formed are, respectively:

    • A.H2OH_2O   and (H2O+O2H_2O + O_2  )Correct
    • B.H2OH_2O   and (H2O+OHH_2O + OH^-  )
    • C.(H2O+O2H_2O + O_2  ) and H2OH_2O
    • D.(H2O+O2H_2O + O_2  ) and (H2O+OHH_2O + OH^-  )
  159. 159
    MCQ4 marks

    The major product formed in the following reaction is:

    • A.Structure 1
    • B.Structure 2
    • C.Structure 3
    • D.Structure 4Correct
  160. 160
    MCQ4 marks

    How long (approximate) should water be electrolysed by passing through 100 amperes current so that the oxygen released can completely burn 27.66 g27.66\text{ g}   of diborane? (Atomic weight of B = 10.8u)

    • A.2 hoursCorrect
    • B.6 hours
    • C.4 hours
    • D.8 hours
  161. 161
    MCQ4 marks

    Which of the following lines correctly show the temperature dependence of equilibrium constant, K, for an exothermic reaction?

    • A.C and D
    • B.A and D
    • C.A and BCorrect
    • D.B and C
  162. 162
    MCQ4 marks

    At 518C518^{\circ}C  , the rate of decomposition of a sample of gaseous acetaldehyde, initially at a pressure of 363 Torr, was 1.00 Torr/s1.00 \text{ Torr/s}   when 5%5\%   had reacted and 0.5 Torr/s0.5 \text{ Torr/s}   when 33%33\%   had reacted. The order of the reaction is:

    • A.1
    • B.0
    • C.2Correct
    • D.3
  163. 163
    MCQ4 marks

    Glucose on prolonged heating with HI gives:

    • A.Hexanoic acid
    • B.6-iodohexanal
    • C.nn  -HexaneCorrect
    • D.1-Hexene
  164. 164
    MCQ4 marks

    Consider the following reaction and statements: [Co(NH3)4Br2]++Br[Co(NH3)3Br3]+NH3[Co(NH_3)_4Br_2]^+ + Br^- \to [Co(NH_3)_3Br_3] + NH_3  . (I) Two isomers are produced if the reactant complex ion is a cis-isomer. (II) Two isomers are produced if the reactant complex ion is a trans-isomer. (III) Only one isomer is produced if the reactant complex ion is a trans-isomer. (IV) Only one isomer is produced if the reactant complex ion is a cis-isomer.

    • A.and (IV)
    • B.and (IV)
    • C.and (II)
    • D.and (III)Correct
  165. 165
    MCQ4 marks

    The major product of the following reaction is:

    • A.Structure 1
    • B.Structure 2Correct
    • C.Structure 3
    • D.Structure 4
  166. 166
    MCQ4 marks

    Phenol on treatment with CO2CO_2   in the presence of NaOH followed by acidification produces compound X as the major product. X on treatment with (CH3CO)2O(CH_3CO)_2O   in the presence of catalytic amount of H2SO4H_2SO_4   produces:

    • A.Structure 1Correct
    • B.Structure 2
    • C.Structure 3
    • D.Structure 4
  167. 167
    MCQ4 marks

    An aqueous solution contains an unknown concentration of Ba2+Ba^{2+}  . When 50 mL50\text{ mL}   of a 1M1\text{M}   solution of Na2SO4Na_2SO_4   is added, BaSO4BaSO_4   just begins to precipitate. The final volume is 500 mL500\text{ mL}  . The solubility product of BaSO4BaSO_4   is 1×10101 \times 10^{-10}  . What is the original concentration of Ba2+Ba^{2+}  ?

    • A.1.1×109 M1.1 \times 10^{-9}\text{ M}Correct
    • B.1.0×1010 M1.0 \times 10^{-10}\text{ M}
    • C.5×109 M5 \times 10^{-9}\text{ M}
    • D.2×109 M2 \times 10^{-9}\text{ M}
  168. 168
    MCQ4 marks

    Which of the following compounds will be suitable for Kjeldahl's method for nitrogen estimation?

    • A.Structure 1
    • B.Structure 2
    • C.Structure 3Correct
    • D.Structure 4
  169. 169
    MCQ4 marks

    When metal MM'   is treated with NaOH, a white gelatinous precipitate XX'   is obtained, which is soluble in excess of NaOH. Compound XX'   when heated strongly gives an oxide which is used in chromatography as an adsorbent. The metal MM'   is:

    • A.AlCorrect
    • B.Fe
    • C.Zn
    • D.Ca
  170. 170
    MCQ4 marks

    An aqueous solution contains 0.10H2S0.10\text{M } H_2S   and 0.20M HCl0.20\text{M HCl}  . If the equilibrium constants for the formation of HSHS^-   from H2SH_2S   is 1.0×1071.0 \times 10^{-7}   and that of S2S^{2-}   from HSHS^-   ions is 1.2×10131.2 \times 10^{-13}   then the concentration of S2S^{2-}   ions in aqueous solution is:

    • A.6×10216 \times 10^{-21}
    • B.5×10195 \times 10^{-19}
    • C.5×1085 \times 10^{-8}
    • D.3×10203 \times 10^{-20}Correct
  171. 171
    MCQ4 marks

    The recommended concentration of fluoride ion in drinking water is up to 1 ppm as fluoride ion is required to make teeth enamel harder by converting [3Ca3(PO4)2Ca(OH)2][3Ca_3(PO_4)_2 \cdot Ca(OH)_2]   to:

    • A.[3Ca3(PO4)2CaF2][3Ca_3(PO_4)_2 \cdot CaF_2]Correct
    • B.[3[Ca(OH)2]CaF2][3[Ca(OH)_2] \cdot CaF_2]
    • C.[CaF2][CaF_2]
    • D.[3(CaF2)Ca(OH)2][3(CaF_2) \cdot Ca(OH)_2]
  172. 172
    MCQ4 marks

    The compound that does not produce nitrogen gas by the thermal decomposition is:

    • A.NH4NO2NH_4NO_2
    • B.(NH4)2SO4(NH_4)_2SO_4Correct
    • C.Ba(N3)2Ba(N_3)_2
    • D.(NH4)2Cr2O7(NH_4)_2Cr_2O_7
  173. 173
    MCQ4 marks

    The predominant form of histamine present in human blood is (pKapK_a   Histidine = 6.0)

    • A.Structure 1
    • B.Structure 2Correct
    • C.Structure 3
    • D.Structure 4
  174. 174
    MCQ4 marks

    The oxidation states of Cr in [Cr(H2O)6]Cl3[Cr(H_2O)_6]Cl_3  , [Cr(C6H6)2][Cr(C_6H_6)_2]  , and K2[Cr(CN)2(O)2(O2)(NH3)]K_2[Cr(CN)_2(O)_2(O_2)(NH_3)]   respectively are:

    • A.+3,0+3, 0  , and +6+6Correct
    • B.+3,0+3, 0  , and +4+4
    • C.+3,+4+3, +4  , and +6+6
    • D.+3,+2+3, +2  , and +4+4
  175. 175
    MCQ4 marks

    Which type of defect has the presence of cations in the interstitial sites?

    • A.Frenkel defectCorrect
    • B.Metal deficiency defect
    • C.Schottky defect
    • D.Vacancy defect
  176. 176
    MCQ4 marks

    The combustion of benzene (l) gives CO2(g)CO_2(g)   and H2O(l)H_2O(l)  . Given that heat of combustion of benzene at constant volume is 3263.9 kJ mol1-3263.9\text{ kJ mol}^{-1}   at 25C25^{\circ}C  ; heat of combustion (in kJ mol1\text{kJ mol}^{-1}  ) of benzene at constant pressure will be: (R=8.314 J K1 mol1R = 8.314\text{ J K}^{-1}\text{ mol}^{-1}  )

    • A.3260
    • B.-3267.6Correct
    • C.6
    • D.-452.46
  177. 177
    MCQ4 marks

    Which of the following are Lewis acids?

    • A.PH3PH_3   and SiCl4SiCl_4
    • B.BCl3BCl_3   and AlCl3AlCl_3Correct
    • C.PH3PH_3   and BCl3BCl_3
    • D.AlCl3AlCl_3   and SiCl4SiCl_4
  178. 178
    MCQ4 marks

    Which of the following compounds contain(s) no covalent bond(s)? KCl,PH3,O2,B2H6,H2SO4KCl, PH_3, O_2, B_2H_6, H_2SO_4

    • A.KClCorrect
    • B.KCl, B2H6B_2H_6
    • C.KCl, B2H6,PH3B_2H_6, PH_3
    • D.KCl, H2SO4H_2SO_4
  179. 179
    MCQ4 marks

    For 1 molal aqueous solution of the following compounds, which one will show the highest freezing point?

    • A.[Co(H2O)4Cl2]Cl2H2O[Co(H_2O)_4Cl_2]Cl \cdot 2H_2O
    • B.[Co(H2O)3Cl3]3H2O[Co(H_2O)_3Cl_3] \cdot 3H_2OCorrect
    • C.[Co(H2O)6]Cl3[Co(H_2O)_6]Cl_3
    • D.[Co(H2O)5Cl]Cl2H2O[Co(H_2O)_5Cl]Cl_2 \cdot H_2O
  180. 180
    MCQ4 marks

    According to molecular orbital theory, which of the following will not be a viable molecule?

    • A.H2H_2^-
    • B.H22H_2^{2-}Correct
    • C.He22+He_2^{2+}
    • D.He2+He_2^+